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  • 儲玲玲:Silver‐Enabled General Radical Difluoromethylation Reaction with TMSCF2H
    發布人:任振夏  發布時間:2020-05-20   

    AbstractA silver‐mediated oxidative difluoromethylation of styrenes and vinyl trifluoroborates with TMSCF 2 H is reported for the first time. This method enables direct and facile access to CF 2 H‐alkenes from abundant alkenes with excellent functional group compatibility . Moreover, this Ag/TMSCF 2 H protocol could further enable a series of radical difluoromethylation of a wide array of substrates, offering a generic and complementary platform for the construction of diversified C‐CF 2 H bonds.